BOOKS OF THE NATIONAL ACADEMY OF SCIENCES OF UKRAINE

Organic photovoltaic structures

Chemistry

Authors:

Bulavko Gennadiy V., Senior Researcher of the Colour and Structure of Organic Compounds Department of the Institute of Organic Chemistry of the National Academy of Sciences of Ukraine, Ph.D. in Chemistry; Associate Professor of Supramolecular Chemistry Department of Educational and Scientific Institute of High Technologies of Taras Shevchenko National University of Kyiv. Institute of Organic Chemistry of the National Academy of Sciences of Ukraine, Ukraine, 02094 Kyiv, Murmanska St., 5; Educational and Scientific Institute of High Technologies of Taras Shevchenko National University of Kyiv, Ukraine, 03022 Kyiv Akademika Hlushkova avenue, 4-g.

ORCID: https://orcid.org/0000-0002-1725-4934

Scopus Author ID: 56095124500

 

Ishchenko Alexander A., Head of the Colour and Structure of Organic Compounds Department of the Institute of Organic Chemistry of the National Academy of Sciences of Ukraine, Professor, Academician of the National Academy of Sciences of Ukraine, Doctor of the Chemical Sciences. Institute of Organic Chemistry of the National Academy of Sciences of Ukraine, Ukraine, 02094 Kyiv, Murmanska St., 5; Educational and Scientific Institute of High Technologies of Taras Shevchenko National University of Kyiv, Ukraine, 03022 Kyiv Akademika Hlushkova avenue, 4-g.

ORCID: https://orcid.org/0000-0003-2722-3944

Scopus Author ID: 8338223800

 

Reviewers:

Kuchmiy Stepan Ya., Head of the Department of Photochemistry, Corresponding member of the National Academy of Sciences of Ukraine, Doctor of the Chemical Sciences. Pisarzhevsky Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Ukraine, 03028 Kyiv, Nauky Ave., 31.

ORCID: https://orcid.org/0000-0002-5576-5858

Scopus Author ID: 6603570730

 

Kolbasov Gennadiy Ya., Head of the Department of Electrochemistry and Fotoelectrochemistry of Non-metallic Systems, Corresponding member of the National Academy of Sciences of Ukraine, Doctor of the Chemical Sciences. V.I. Vernadsky Institute of General and Inorganic Chemistry of the National Academy of Sciences of Ukraine, Ukraine, 03142 Kyiv, Academician Palladin Ave., 32/34.

ORCID: https://orcid.org/0000-0001-9208-2135

Scopus Author ID: 7003674961

 

Affiliation:

Project: Scientific book

Year: 2022

Publisher: PH "Naukova Dumka"

Pages: 208

DOI:

https://doi.org/10.15407/978-966-00-1839-6

ISBN: 978-966-00-1839-6

Language: Ukrainian

How to Cite:

Bulavko, G., Ishchenko, A. (2022) Organic photovoltaic structures. Kyiv, Naukova Dumka. 208p. [in Ukrainian].

Abstract:

It is summarized and systematized the main approaches to creation of organic bulk heterojunction photovoltaic structures in the monograph. New photovoltaic materials based on fullerenes, conjugated polymers, organic dyes, graphenes and dendrimers are considered. The main attention is paid to the relationship between structure and material property. The morphology influence of the photoactive layer on the photovoltaic characteristics of solar cells is analyzed. The main ways of optimizing these characteristics are considered. The factors that determine them are identified and analyzed. New effects in organic photovoltaics – photocurrent hysteresis and photovoltaic effect of optically transparent materials – are discussed. Much attention is paid to the use of quantum chemical calculations for the interpretation of photovoltaic effects. The ways of purposeful design of new photovoltaic organic structures are proposed. The monograph will be useful to researchers and engineers working in the field of photonics, organic semiconductors, macromolecular compounds, organic chemistry, electronic structure of molecules and materials for photovoltaics, as well as university teachers, graduate students and students of chemical, physical and materials science profile.

Keywords:

photovoltaic structures; organic semiconductors; photoconductive polymers; polymethine dyes; electronic structure; spectral-fluorescence properties; electron-hole pairs; dissociation and recombination; frontier molecular orbitals

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